Emulsion polymerization is one of the most important methods for the polymerization of a large number of monomers, like vinyl acetate, vinyl chloride, chloroprene,acrylamide, acrylates, and methacrylates. It is also used for the production of various copolymers, like acrylonitrile-butadiene-styrene (ABS).
Emulsion polymerization has several advantages over other polymerization techniques; for example, it is more rapid than bulk or solution polymerization at the same temperature, the conversion is essentially 100 percent, and the average molecular weight is usually (much) higher than at the same polymerization rate in bulk or solution polymerization. Also, heat dissipation and viscosity control are much less problematic than in bulk polymerization.
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